Water vapour based systems 
These use water as refrigerant. Water is a highly effective refrigerant (better than most CFCs, HCFCs, HFCs) but has the disadvantage of a very low vapour density and low evaporating pressure which makes its use in conventional vapour compression systems impracticable. Recent attempts to overcome these problems have either used ejectors or turbo compressors. 

Ejectors typically use steam passing through an expansion nozzle to entrain a secondary flow of water vapour from an evaporator vessel at low pressure and raise its pressure at the ejector discharge. The driving energy is heat to raise the steam that drives the compression process. There are therefore few moving parts and the system can be powered by waste heat or even solar energy. A major disadvantage is the low efficiency of ejectors which leads to low overall COPs (coefficient of performances). The University of Nottingham has built a prototype system that has been installed in a building in Leicestershire using solar panels and a back up gas fired boiler. Its COP is only around 0.3 but this does not matter when the system is being powered by solar energy. More crucial is the high capital cost of the prototype although the University is investigating how ejectors may be moulded from plastic which should reduce the cost of manufactured systems. 
 

Figure 1 an Expansion-cooling Module 


 A prototype turbo compressor system has been installed at the LEGO factory in Denmark. This uses a two-stage turbo compressor to compress the very high volume of water vapour needed for its 2 MW cooling capacity. As a prototype the cost of the system was very high at around £4650 / kW compared to £50 - £100 / kW for conventional chillers. However, its COP is claimed to be higher than conventional R22 chillers. It remains to be seen whether the very high capital cost could be reduced by using modern mass production techniques. 

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